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September 1967 Electronics World
Table
of Contents
Wax nostalgic about and learn from the history of early electronics. See articles
from
Electronics World, published May 1959
- December 1971. All copyrights hereby acknowledged.
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This 1967 Electronics
World magazine article highlights a potential revolution in microwave technology
through new semiconductor devices that could miniaturize and drastically reduce
the cost of microwave sources. The focus is on two promising devices: the Read p-n
junction diode and the Gunn bulk gallium arsenide oscillator. The Gunn device, discovered
accidentally by Dr. J.B. Gunn at IBM, operates on a radical principle - a bulk
semiconductor material oscillates at microwave frequencies without external tuned
circuitry when a threshold voltage is applied. Key to the Gunn effect is the unique
property of gallium arsenide, which features a second conduction band. Electrons
entering this high-energy, low-mobility band create "domains" that drift slowly
from cathode to anode, causing current oscillations. This generates microwave frequencies
based on the domain's transit time across the material. Though simpler and cheaper
than existing devices, the Gunn oscillator faced challenges in power output and
reliability. The article concludes that while it was uncertain which device would
dominate, the Gunn effect represented a significant breakthrough poised to enable
new consumer microwave applications. Note the "waterfall" chart in Figure 3,
which was not referred to as such because the term did not appear until the 1990s
when finance and management firms coined the name.
Gunn Oscillators

The larger device is intended for the Gunn bulk oscillator, while
the smaller device houses a Read-type junction diode
By David L .Heiserman
A new type of microwave semiconductor that may one day replace present complex
and expensive sources, and create new consumer microwave communications and radar
devices.
There is little doubt in the minds of semiconductor scientists and engineers
that microwave technology is on the threshold of a miniaturization and cost revolution.
A new breed of simple microwave semiconductors may one day replace our present complex
and expensive microwave sources and create a whole new line of consumer microwave
communications and radar devices.
The makers of the revolution will be the new transit-time semiconductors best
represented by the Read p-n junction diode and the Gunn bulk gallium arsenide oscillator.
( See "New Frontiers in Semiconductors" on page 78 of the March, 1967 issue.) At
this stage of development, however, no one can say which device will eventually
set the micro-wave revolution into motion - both have advantages and disadvantages,
and both are plagued by production reliability problems.
The theories of operation of both devices are rather new. The Read-type device
operates on the well -known principles of the zener and tunnel diodes with the new
idea of semiconductor electron transit time tying the two effects together. The
operation of the Gunn device, however, represents a radical departure from conventional
semiconductor thinking. In this respect, the Gunn device is worthy of closer study.

Fig. 1 - The current through bulk GaAs increases with an increasing
amount of applied d.c. voltage until the conduction band electrons gain enough energy
to skip upward into high energy, low-mobility band. At this threshold voltage (about
3000 volts /cm or about 6 volts of applied voltage) the GaAs sample will oscillate
without any external tuned circuitry.

Fig. 2 - The quantum- energy diagram (shown in the inset) along
with a corresponding current-voltage curve for bulk gallium arsenide are illustrated
below. The existence of the second forbidden gap and the low- mobility, high- energy
conduction band gives GaAs quite different properties from the usual semiconductor,
such as n -doped silicon, showing no negative R.

Table 1 - Performance of Gunn and other microwave devices.
Gunn's Discovery
Those of us who have been working in electronics for more than a few years associate
semiconductor devices with one or more p-n junctions. We think in terms of holes
and electrons, minority and majority carriers, junction potentials - always in terms
of at least one pair of p and n semiconductor materials within one device. To think
of an operational semiconductor made up of only one type of semiconducting material
(a bulk semiconductor) is, traditionally, to think of an impossibility. Despite
conventional thinking, the "impossible" was accidentally discovered by Dr. J.B.
Gunn at IBM's Watson Research Center.
In 1963, Gunn was running a series of routine experiments on a 0.005-inch thick
slice of homogeneous n -type gallium arsenide when he noticed some unexpected coherent
r.f. oscillations on his oscilloscope. Checking the setup for possible stray reactance
or faulty components, he discovered that the plain n-doped material was oscillating
at slightly less than 1 GHz (1000 MHz) with nothing more than a 6-volt d.c. power
supply connected to the terminals (Fig. 1). What had been a purely theoretical possibility
became a fact - Gunn found a semiconductor material that could oscillate in the
microwave region without benefit of external tuned circuitry.
Gunn and his associates soon realized that they had uncovered a phenomenon that
could not be explained in terms of the usual semiconductor theories, so they were
forced to try new theories and experimental techniques. The theoretical model of
the oscillator, as finally developed, represents one of the biggest sidesteps from
the mainstream of semiconductor thinking since the introduction of the laser diode.
Negative Resistance in Bulk GaAs
Without the benefit of the usual p-n junction, the Gunn oscillator demonstrates
negative resistance properties. The quantum energy diagram and corresponding I-V
curve are shown in Fig. 2. The diagram shows the usual forbidden gap between the
valence and normal conduction bands. These regions in GaAs have the characteristics
of any other n-type semiconductor such arsenic-doped silicon. The GaAs, however,
has an additional forbidden gap and a special conduction band that differs from
the first in two important respects. First, carriers (electrons in the case of GaAs)
can cross the second forbidden gap only when the applied d.c. potential reaches
an extraordinarily high value of 3000 volts per centimeter. Second, carriers that
do gain enough energy to skip into the second conduction band effectively gain some
mass and thus travel much more slowly through the semiconductor than their lower
energy counterparts in the first conduction band.
The second conduction band is thus described as one containing only high-energy
carriers which travel with un- usual slowness through the semiconductor. It is this
additional conduction band that makes it possible for an n -type bulk semiconductor
to show negative resistance.
Referring to the I-V curve in Fig. 2, the nonlinear slope between points A and
B is due to the increasing fraction of valence electrons skipping upward into the
high-mobility first (normal) conduction band under the influence of a small applied
voltage.
As the applied e.m.f. is increased beyond point B, however, the current drops
off sharply. It is at this point that some of the electrons in the low-energy, high
-mobility first conduction band enter the high-energy, low-mobility second conduction
band. If electrons move slower in the second conduction band than they can in the
first, it follows that increasing the percentage of electrons in the second conduction
band will cause a corresponding decrease in the net rate of electron flow through
the material. As the applied voltage passes beyond point B, then, the current through
the GaAs sample decreases. This, of course, is the general description of a negative-
resistance effect.

Fig. 3 - The low-mobility, high-energy electron domain passing
through the Gunn device. The domain builds up near the cathode and moves with relative
slowness to the anode, holding the current through the semiconductor to a minimum.
Although the ordinate of the oscillogram is in terms of field strength, the downward
progression of traces has no physical meaning except to display the chronology of
the shock wave that is produced.
The negative-resistance, junction-type semiconductors in use today require some
capacitance or inductance to sustain oscillation while the Gunn device does not.
So, negative resistance in bulk semiconductor theories are potentially useful, but
cannot wholly account for the Gunn effect.
Electron Domain Transit Time
Electron Domain Transit Time The theory that finally rounded out the explanation
of the Gunn effect involves the new concept of slow-moving, high-energy packets
or "domains" within a bulk semiconductor.
If a sufficient voltage (the threshold voltage) is applied to a thin slice of
n-type GaAs, electrons skipping into the second conduction band tend to collect
into discrete energy domains. Further, if the GaAs is of sufficient purity and the
applied voltage is carefully regulated, one and only one domain can exist within
the material at any one instant.
Since this one domain is made up of second conduction band electrons, the domain
will behave exactly as the electrons described in connection with Fig. 2. The domain
will drift with relative slowness from cathode to anode, holding the net current
flow through the semiconductor to a minimum.
Once the domain reaches the anode, it disappears momentarily and current surges
through the material via the first conduction band. This surge continues until another
high-energy, low-mobility domain forms at the cathode. The current through the bulk
semiconductor, then, is low during the electron domain transit time and relatively
high during the brief period of time it takes to form another domain at the cathode.
Thus, the Gunn device demonstrates current oscillations, the period of which depends
on the rate of domain travel and the physical length of the bulk semiconductor material.
The oscillogram of Fig. 3 shows the high-energy domain passing through discrete
points along the length of a thin slice of bulk GaAs. The trace at the top shows
the domain leaving the cathode. In the following traces, the moving electron domain
is shown at points progressively closer to the anode. If the frequency of oscillation
is assumed to be about 1 GHz, the traces cover an interval of about 1 μs.
At the present stage of semiconductor technology, the Gunn device's advantages
of small size, low cost, and simplicity must be weighed against the disadvantages
of lower operating frequency and low c.w. output power. Placed beside the Read-type
devices, the Gunn oscillator has about a 50 percent chance of becoming the microwave
source of the future. See Table 1.
Regardless of the final outcome, the Gunn effect described in this article represents
another opening to products and industrial equipment thought impossible a few years
ago.
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